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Improving enantioselectivity via rationally tuning electronic effect of catalysts in the organocatalytic asymmetric aldol reaction

机译：通过合理调整有机催化不对称羟醛反应中催化剂的电子效应来提高对映选择性

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Juanjuan Du; Zhiyi Li; Da-Ming Du; Jiaxi Xu;
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1. 2,4-Dinitrophenol as an Effective Cocatalyst: Greatly Improving theActivities and Enantioselectivities of Primary AmineOrganocatalysts for Asymmetric Aldol Reactions [J] . Chao-Shan Da, Li-Ping Che, Qi-Peng Guo, The Journal of Organic Chemistry . 2009,第6期

机译：2,4-二硝基苯酚作为有效的助催化剂：极大地提高了伯胺有机物催化剂的不对称羟醛反应的活性和对映选择性
2. Organocatalytic Enantioselective Michael-Michael-Michael-Aldol Condensation Reactions: Control of Six Stereocenters in a Quadruple-Cascade Asymmetric Synthesis of Polysubstituted Spirocyclic Oxindoles [J] . Chaudhari Prakash D., Hong Bor-Cherng, Lee Gene-Hsiang Organic letters . 2017,第22期

机译：有机催化对映选择性Michael-Michael-Michael-Aldol缩合反应：控制六个立体封闭在多元级联的不对称合成的六个立体沉积物的多助药梭菌豆类
3. Organocatalytic Enantioselective Michael?Michael?Michael?Aldol Condensation Reactions: Control of Five Stereocenters in a Quadruple-Cascade Asymmetric Synthesis of Highly Functionalized Hexahydrophenanthrenes [J] . Arun Raja, Bor-Cherng Hong, Gene-Hsiang Lee Organic letters . 2014,第21期

机译：有机催化对映选择性Michael？Michael？Michael？Aldol缩合反应：高功能化六氢菲四级联非对称合成中五个立体中心的控制。
4. An Asymmetric Organocatalytic Domino-Michael-Aldol Reaction [C] . Alexander Kuenkel, Francisco Tato, Magnus Rueping European Symposium on Organic Chemistry . 2009

机译：不对称有机催化多米诺 - Michael-aldol反应
5. Part I. Asymmetric organocatalysis: (1) Direct enantioselective organocatalytic hydroxymethylation of aldehydes catalyzed by alpha,alpha-diphenylprolinol trimethylsilyl ether: Application in the formal synthesis of (-)-Rasfonin; (2) Synthesis of a novel bicyclic secondary amine organocatalyst: Application to the direct enantioselective organocatalytic hydroxymethylation of aldehydes. Part II. Asymmetric synthesis of bicyclic analogues of the anti-osteoporotic drug risedronate. [D] . Miller, John Robert. 2010

机译：第一部分，不对称有机催化：（1）α，α-二苯基脯氨醇三甲基甲硅烷基醚催化的醛的直接对映选择性有机催化羟甲基化：在（-）-Rasfonin的正式合成中的应用；（2）新型双环仲胺有机催化剂的合成：应用于醛的直接对映选择性有机催化羟甲基化。第二部分抗骨质疏松药物Risedronate的双环类似物的不对称合成。
6. Asymmetric Catalysis Special Feature Part I: Air-stable storable and highly efficient chiral zirconium catalysts for enantioselective Mannich-type aza Diels–Alder aldol and hetero Diels–Alder reactions [O] . Shū Kobayashi, Masaharu Ueno, Susumu Saito, 2004

机译：不对称催化的特殊功能（第一部分）：对映选择性曼尼希型氮杂Diels–AlderAldol和杂Diels–Alder反应的空气稳定可储存且高效的手性锆催化剂
7. Highly Enantioselective Organocatalytic Asymmetric Mukaiyama-aldol Reaction of Difluoroenoxysilanes withβ,γ-Unsaturatedα-Ketoesters [O] . Yunlin Liu, Jian Zhou 2012

机译：高映选择性有机催化不对称的非对称Mukaiyama-Aldol与β，γ-不饱和α-酮甾体的二氟苯氧基硅烷反应

Improving enantioselectivity via rationally tuning electronic effect of catalysts in the organocatalytic asymmetric aldol reaction

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